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Hydrodesulfurization/Hydroprocessing

 

CDTECH®, a partnership of Lummus Technology and Chemical Research & Licensing Co., offers several commercially proven catalytic distillation processes for the hydroprocessing of various refinery streams.

The combination of the CDHydro(1) hydrogenation and CDHDS(1) /CDHDS+(1) dehydrodesulfurization processes is a low capital cost and operating cost solution to effectively reduce the sulfur level of full-range FCC naphtha while retaining most of the octane value of the FCC naphtha without yield loss. Sulfur content is reduced by more than 99%, allowing refiners to meet even the most severe gasoline sulfur regulations.

The CDHydro process selectively hydrogenates various refinery and steam cracker streams:

  • C3+ streams from steam crackers to produce a C3 stream that is essentially free of methyl acetylene and propadiene (MAPD) (selective hydrogenation of MAPD to propylene).
  • C4 streams from refineries to produce a stream with a high butylenes content that is essentially free of butadiene (selective hydrogenation of butadiene to normal butenes). The treated C4 stream is suitable for MTBE production, butene-1 production, or alkylation feed.
  • C4 streams from refineries or steam crackers within an MTBE/ETBE debutanizer to produce a raffinate with a high butylenes content that is essentially free of butadiene (selective hydrogenation of butadiene to normal butenes).
  • C5 streams from refineries to produce a stream with a high isoamylenes content that is essentially free of diolefins (selective hydrogenation of the diolefins to amylenes). The treated C5 stream is suitable for TAME production or alkylation feed.
  • Reformate streams from refineries to reduce benzene to levels required in reformulated gasoline (hydrogenation of benzene to cyclohexane).

(1) CDHydro, CDHDS+ and CDHDS are registered trademarks of CDTECH.

Tech Sheet

Selective FCC Gasoline Sulfur Reduction CDHydro®, CDHDS®, and CDHDS+SM (pdf 156KB)